No, you can't use MKIV rotors on a MKIII with MKIV rear calipers, they won't work with the MKIII stub axles.
You don't have to replace the MKIII rear brake rotors (and wheel bearings) unless they are worn-out. But, if the MKIII brake rotors are worn-out, it's always a good idea to buy and install new wheel bearing kits in the new brake rotors you get.
Infact, on a MKIII upgrading to MKIV rear calipers, the only MKIV parts that are used are the MKIV rear calipers themselves.
The other MKIV rear brake parts (caliper carriers, brake pads, caliper mounting bolts, brake rotors, and stub axles) don't even fit on a MKIII.
You use the MKIII brake pads, caliper carriers, caliper mounting bolt, splash plates, parking brake cables, stub axles, and brake rotors with wheel bearings.
You have your choice of using the one piece MKIV hybrid flexhose/metal hardlines that run from the calipers to the front of the trailing arms, OR keeping the MKIII rear disc brake hardlines, and buying the flex hoses from a Passat to connect the MKIV rear calipers to the MKIII metal hard lines.




